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Synthesis,characterization of Fe3O4@glycine doped polypyrrole magnetic nanocomposites and their potential performance to remove toxic Cr(VI)
Affiliation:1. Department of Applied Chemistry, University of Johannesburg, South Africa;2. Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea;3. Smart Polymers Group, Polymers and Composites (P&C), Materials Science and Manufacturing (MSM), Council for Scientific and Industrial Research (CSIR), Pretoria, South Africa;4. Department of Civil and Chemical Engineering, University of South Africa (UNISA), South Africa;1. Department of Physics, Southeast University, Nanjing 211189, China;2. College of Physics and Technology,Yunnan University, Kunming 650091, China;3. Department of Physics and Key Laboratory of Yunnan Provincial Higher Education Institutions for Organic Optoelectronic Materials and Devices, Kunming University, Kunming 650214, China;1. Departamento de Física, Universidade Federal de Pernambuco, 50670-901 Recife, PE, Brazil;2. Departamento de Química, Pontifícia Universidade Católica do Rio de Janeiro, 22451-900 Rio de Janeiro, RJ, Brazil;3. Departamento de Bioquímica, Universidade Federal de Pernambuco, 50670-901 Recife, PE, Brazil;4. Departamento de Engenharia Mecânica, Universidade Federal de Pernambuco, 50670-901 Recife, PE, Brazil
Abstract:Fe3O4 coated glycine doped polypyrrole magnetic nanocomposite (Fe3O4@gly-PPy NC) was prepared via coating of suspended Fe3O4 nanoparticles with gly-PPy. FE-SEM and HR-TEM images indicated that Fe3O4 nanoparticles were encapsulated by precipitating gly-PPy moieties. Chromium(VI) adsorption followed a Langmuir isotherm with maximum capacity of 238–303 mg/g for a temperature range of 25–45 °C at pH 2. The adsorption process was governed by the ionic interaction and the reduction of Cr(VI) to Cr(III) by the PPy moiety. Results showed that NCs are effective adsorbents for the removal of Cr(VI) from wastewater and can be separated by external magnetic field from the reactor.
Keywords:Polypyrrole  Glycine  Magnetic nanocomposite  Hexavalent chromium  Adsorption
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