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Polymer material-supported titania nanofibers with different polyvinylpyrrolidone to TiO2 ratios for degradation of vaporous trichloroethylene
Affiliation:1. Department of Naval Architecture and Ocean Engineering, Pusan National University, 63 Jangjeon-dong, Geumjeong-gu, Busan 609-735, South Korea;2. Department of Environmental Engineering, Kyungpook National University, 80 University Road, Bukgu, Daegu 702-701, South Korea;1. Crystal Lab, Department of Physics and Astrophysics, University of Delhi, Delhi 110007, India;2. Department of Electronics, SGTB Khalsa College, University of Delhi, Delhi 110007, India;1. School of Chemical Engineering and Analytical Science, The University of Manchester, M60 1QD, UK;2. Arvia Technology Limited, Daresbury Innovation Centre, Keckwick Lane, Daresbury, Cheshire, WA4 4FS, UK;3. Department of Chemical and Petroleum Engineeirng, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada;1. Department of Polymer Chemistry, National Center for Radiation Research and Technology, Nasr City, Cairo, Egypt;2. Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt;1. Department of Materials Science and Engineering, Hongik University, Seoul 121-791, South Korea;2. Fusion Energy Group, Future Technology Research Laboratory, Korea Electric Power Research Institute (KEPRI), Korea Electric Power Corporation (KEPCO), Daejeon, South Korea;1. School of Environmental & Municipal Engineering, North China University of Water Resources and Electric Power, ZhengZhou, He’nan 450011, People’s Republic of China;2. College of Chemistry & Chemical Engineering, YangZhou University, YangZhou, Jiangsu 225002, People’s Republic of China
Abstract:Polymer-supported TiO2 nanofibers with different polyvinylpyrrolidone (PVP)-to-TiO2 (PT) ratios were synthesized and their photocatalytic efficiencies were examined for the decomposition of trichloroethylene (TCE). The spectral results of the TiO2 nanofibers confirmed the presence of TiO2 crystal phases in the nanofibers. The TiO2 nanofiber with the highest PT ratio of 1:1.3 showed the highest TCE decomposition (94%), followed by TiO2 nanofibers with PT ratios of 1:0.7 (91%), 1:0.35 (88%), and 1:0.1 (84%). The conditions of low input concentration and humidity were suggested for the optimal decomposition of TCE. Consequently, the TiO2 nanofiber webs could be used effectively to decompose TCE.
Keywords:Polyvinylpyrrolidone  Polymer ratio  Nanofiber web  Gaseous trichloroethylene
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