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Surfactant flooding characteristics of dodecyl alkyl sulfate for enhanced oil recovery
Affiliation:1. Department of Chemical and Biochemical Engineering, Dongguk University, 3-26, Pil-dong, Chung-gu, Seoul 100-715, Republic of Korea;2. Department of Petroleum Engineering, Universiti Teknologi Malaysia, 81310 Skudai, Johor, Malaysia;1. Department of Petroleum Engineering, Ahwaz Faculty of Petroleum Engineering, Petroleum University of Technology, Ahwaz, Iran;2. Department of Petroleum Engineering, Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, Iran;1. Department of Petroleum Engineering, Indian School of Mines, Dhanbad 826004, India;2. Department of Chemical Engineering, Indian School of Mines, Dhanbad 826004, India;3. Department of Civil & Environmental Engineering, School of Mining & Petroleum Engineering, University of Alberta, Edmonton, Canada T6G 2W2
Abstract:Surfactant-enhanced oil recovery is a type of enhanced oil recovery (EOR), a method to produce residual oil by injecting surfactant solution into the reservoir. The application of surfactant EOR requires knowledge of the phase behavior for more efficient production of residual oil.In this study, the relationship between dodecyl alkyl sulfate and some specific crude oils was examined through phase behavior test. It was found that the branched surfactant was more effective than the linear surfactant. The system was stable at salinities <3 wt%. On adding a small amount of co-surfactant, the emulsion activity was increased.The gravity drainage flooding test (GDFT) was performed to determine the potential of dodecyl alkyl sulfate to produce residual oil in porous media. It was found that the solution could be flooded at temperatures of 60 °C or higher. In the core flooding test, injecting one pore volume of 2 wt% surfactant solution with 3 wt% salinity produced 26.6% more oil after water flood. With the addition of only 0.01 wt% co-surfactant, oil production increased by 1.6%. Contrary to the phase behavior test, the linear surfactant produced 1.3% more oil than the branched surfactant in the core flooding test.
Keywords:Enhanced oil recovery (EOR)  Surfactant EOR  Dodecyl alkyl sulfate  Phase behavior test  Gravity drainage flooding test (GDFT)
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