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Preparation of porous and hollow Mn2O3 microspheres and their adsorption studies on heavy metal ions from aqueous solutions
Affiliation:1. Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtse River), Ministry of Agriculture, College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China;2. Department of Soil Quality, Wageningen University, P.O. Box 8005, 6700 EC Wageningen, The Netherlands;3. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China
Abstract:Mn2O3 microspheres are prepared and used as adsorbent for removal of heavy metal ions. Morphology and structure of Mn2O3 microspheres are analyzed by SEM, TEM, XRD, XPS and N2 sorption technique. Effects of adsorbent concentration, ion concentration and agitation time on adsorption behavior are investigated. Adsorption isotherm and kinetics are also studied. The results show Mn2O3 microspheres have well-developed porous and hollow structure, demonstrating good potential on removal of heavy metal ions. Adsorption data fit better with Freundlich isotherms than Langmuir isotherms. Kinetic studies indicate adsorption behavior is described by pseudo-second-order kinetic model, and intra-particle diffusion plays a significant role.
Keywords:Preparation  Removal  Isotherm  Kinetics
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