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Application of kinetic,isotherm and thermodynamic models for the adsorption of Co(II) ions on polyaniline/polypyrrole copolymer nanofibers from aqueous solution
Affiliation:1. Department of Chemical Engineering, Faculty of Engineering, University of Ilam, Ilam, Iran;2. Department of Chemical Engineering, Faculty of Engineering, Babol University of Technology, Babol, Iran;3. Department of Chemical Engineering, University of the Basque Country, Bilbao, Spain;4. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi 110025, India
Abstract:The aim of this research is to investigate sorption characteristics of polyaniline/polypyrrole copolymer nanofibers (PANI/PPy copolymer nanofibers) for the removal of Co(II) ions from aqueous solution. The adsorbent is characterized using FE-SEM, TEM, FTIR, TGA, DSC and BET surface area. The sorption of Co(II) ions by batch method is applied and the optimum conditions are investigated. In optimum condition, removal efficiency was 99.68% for 100 mg L?1 Co(II) solution. It is found that temperature has a positive effect on the removal efficiency. It can be concluded that PANI/PPy copolymer nanofibers are potentially able to removal of Co(II) ions from aqueous solutions.
Keywords:Adsorption  Nanofiber  Cobalt  Kinetic  Isotherm  Thermodynamic
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