|
|||||
|
|
| N,N′-双月桂酰基乙二胺二乙酸钠合成方法的改进 | |
| 引用本文： | 黄智,李成海,梁宇宁,韩朔暌,王连生. N,N′-双月桂酰基乙二胺二乙酸钠合成方法的改进[J]. 精细化工, 2002, 19(1): 1-3 |
| 作者姓名： | 黄智 李成海 梁宇宁 韩朔暌 王连生 |
| 作者单位： | 1. 南京大学环境学院,江苏,南京,210093 2. 广西大学化学系,广西,南宁,530004 3. 广西师范大学,化学系,广西,桂林,541004 |
| 摘 要： | 对表面活性剂N ,N′ 双月桂酰基乙二胺二乙酸钠的合成方法进行了改进。以乙二胺与氯乙酸钠反应制备乙二胺N ,N′ 二乙酸钠 (中间体 ) ,再与月桂酰氯反应制备终产物N ,N′ 双月桂酰基乙二胺二乙酸钠。用正交法对合成条件进行了探索。合成中间体最佳条件为温度 2 5℃ ,n(氯乙酸 )∶n(乙二胺 ) =(3 15～ 3 45 )∶1 0 0 ,反应时间 2 4h。终产物的合成条件为温度 15℃ ,反应时间为 2 4h。以IR、13CNMR和1HNMR确定结构 |
| 关 键 词： | 表面活性剂 乙二胺 |
| 文章编号： | 1003-5214(2002)01-0001-03 |
| 修稿时间： | 2001-02-28 |
Improvement on the Synthetic Method of N,N′-Dilauroylethylenediamine-diacetic Acid |
|
| HUANG Zhi ,LI Cheng hai ,LIANG Yu ning ,HAN Shuo kui ,WANG Lian sheng. Improvement on the Synthetic Method of N,N′-Dilauroylethylenediamine-diacetic Acid[J]. Fine Chemicals, 2002, 19(1): 1-3 | |
| Authors: | HUANG Zhi LI Cheng hai LIANG Yu ning HAN Shuo kui WANG Lian sheng |
| Affiliation: | HUANG Zhi 1,LI Cheng hai 2,LIANG Yu ning 3,HAN Shuo kui 1,WANG Lian sheng 1 |
| Abstract: | There was some improvement on the synthetic method of N,N ′ dilauroyl ethylenediamine diacetic acid.Ethylenediamine reacted with chloroacetic acid to form the intermediate sodium ethylenediamine N,N ′ diacetate which then reacted with lauroyl chloride to give N,N ′ dilauroyl ethylenediamine diacetic acid.The optimum reaction conditions were determined by orthogonal test.For the intermediate,chloroacetic acid and ethylenediamine in mole ratio 3.15-3.45 reacted at 25 ℃ for 24 h.For the final product,the reaction was carried out at 15 ℃ for 24 h.Structure of the product was certified by +1 HNMR,+{13}CNMR and IR. |
| Keywords: | surfactant ethylenediamine |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |