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| 聚电解质溶液的分子热力学模型 | |
| 引用本文： | 姜建文 陈怡昭. 聚电解质溶液的分子热力学模型[J]. 高校化学工程学报, 1999, 13(2): 95-100 |
| 作者姓名： | 姜建文 陈怡昭 |
| 作者单位： | 华东理工大学化学系!上海２００２３７ |
| 基金项目： | 国家自然科学基金，国家教委博士学科点专项科研基金 |
| 摘 要： | 采用事电柔性硬球链近似链状聚离子，从微扰理论和离子缔合理论出发，建立了链状聚电解质溶液的分子热力学模型，并引入聚离子与反离子间的缔合以计及短程作用。成功地计算了聚电解质溶液的热力学性质，所得结果与计算机模拟数据、实验结果吻合。 |
| 关 键 词： | 聚电解质溶液 微扰理论 分子热力学模型 |
Molecular Thermodynamic Model for Polyelectrolyte Solution |
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| Jiang Jianwen, Chen Yizhao, Liu Honglai, Hu Ying. Molecular Thermodynamic Model for Polyelectrolyte Solution[J]. Journal of Chemical Engineering of Chinese Universities, 1999, 13(2): 95-100 | |
| Authors: | Jiang Jianwen Chen Yizhao Liu Honglai Hu Ying |
| Abstract: | The linear flexible polyions are mimicked as flexible charged hard-sphere chains, andthe molecular thermodynamic model is established combining perturbation theory and sticky electrolytemodel. Beyond the electrostatic potential, the additional stickiness between polyions and counterions istaken into account as short-range non-coulombic interaction. The thermodynamic properties for modelsolutions and real systems are calculated, and satisfactory agreements among the calculated results bypresent model, those from computer simulation and experimental results are observed. |
| Keywords: | Polyelectrolyte solution Perturbation theory Integral equation Molecular thermodynamic model |
| 本文献已被 CNKI 维普 等数据库收录！ | |