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程序升温还原法和程序升温脱附法表征全Pd催化剂
引用本文:赵彬.程序升温还原法和程序升温脱附法表征全Pd催化剂[J].贵金属,2011,32(1).
作者姓名:赵彬
作者单位:四川理工学院,四川自贡,643000
基金项目:四川省教育厅科研基金项目
摘    要:研制的新型储氧材料具有高的储氧量和大的比表面积,显示出良好的抗高温老化性能.将新型的储氧材料作为载体添加到Pd/Al2O3催化剂中,用程序升温还原法(TPR)和程序升温脱附法(TPD)对催化剂Pd/Al2O3、Pd/OSZ及Pd/Al2O3+OSZ性能进行表征,表明储氧材料的添加,影响了Pd的氧化还原性能和氧脱附性能,提高了催化剂的活性.

关 键 词:物理化学  储氧材料  钯三效催化剂  程序升温还原法(TPR)  程序升温脱附法(TPD)

Characterization of Pd Catalysts by Temperature Programmed Reduction and Temperature Programmed Desorption
ZHAO Bin.Characterization of Pd Catalysts by Temperature Programmed Reduction and Temperature Programmed Desorption[J].Precious Metals,2011,32(1).
Authors:ZHAO Bin
Affiliation:ZHAO Bin (Sichuan University of Science and Engineering,Zigong 643000,Sichuan,China)
Abstract:The novel oxygen storage components were prepared and studied.It was proved that the new material has large surface area,high oxygen storage capacity and good performance of high-temperature-resistant.The active component-support interactions of Pd/Al2O3,Pd/OSZ and Pd/Al2O3+OSZ catalysts were studied via temperature programmed reduction(TPR) and temperature programmed desorption(TPD).The results show that the addition of novel oxygen storage components to the Pd/Al2O3 improves the thermal stability of Pd an...
Keywords:physical chemistry  oxygen storage components(OSZ)  palladium three-way catalysts  temperature programmed reduction(TPR)  temperature programmed desorption(TPD)  
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