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从铜镉渣中回收铜
引用本文:曾懋华,奚长生,彭翠红,龙来寿. 从铜镉渣中回收铜[J]. 过程工程学报, 2004, 4(4): 314-319
作者姓名:曾懋华  奚长生  彭翠红  龙来寿
作者单位:韶关学院化学系,广东,韶关,512005;广东工业大学轻工化工学院,广东,广州,510080
基金项目:广东省教育厅自然科学基金资助资助项目(编号:1999-89)
摘    要:对不同的金属还原剂从铜镉渣中置换铜进行了研究,提出了用新制海绵镉置换铜的新方法,减少了共存离子的置换,有效地防止了有毒气体的生成. 用含铜2%的铜镉渣制得了纯度高达95%的海绵铜,铜的回收率达到99%以上.

关 键 词:铜镉渣  置换  新制海绵镉  海绵铜
文章编号:1009-606X(2004)04-0314-06
修稿时间:2003-08-04

Recovery of Copper from Copper and Cadmium Sediment
ZENG Mao-hua,XI Chang-sheng,PENG Cui-hong,LONG Lai-shou. Recovery of Copper from Copper and Cadmium Sediment[J]. Chinese Journal of Process Engineering, 2004, 4(4): 314-319
Authors:ZENG Mao-hua  XI Chang-sheng  PENG Cui-hong  LONG Lai-shou
Affiliation:Department of Chemistry, Shaoguan University
Abstract:The displacement of copper from copper and cadmium sediment by different metallic reducing agents was studied. The result of experiment showed that the displacement of copper by zinc was not the optimum technique, and the displacement of copper by fresh sponge cadmium was better. A new method of displacement of copper using fresh sponge cadmium was presented. The new method has some advantages which reduced the displacement of coexistence ion and prevented the release of poisonous gas effectively. Some important facts which affect reaction were researched, for example, the quantity of metallic reducing agent, the time of reaction and the temperature of reaction etc. The sponge copper was obtained from acid solution of copper and cadmium sediment which contained 2% copper by fresh sponge cadmium and the purity of sponge copper was 95%, the recovery of copper was over 99%.
Keywords:copper and cadmium sediment  displacement  fresh sponge cadmium  sponge copper
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