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Decontamination of petroleum sludges by hot water extraction
Authors:Francis T. Tran  Denis Couillard  Denis Rouleau
Abstract:The process of hot water extraction of tar sand was modified and adapted for removal of heavy oil from bottom tank petroleum sludges, and was submitted to a laboratory feasibility study. This process can also be utilized to clean beach sands contaminated by accidental heavy oil spills. In the case of oil contaminated sands, a single stage extraction has yielded a 99% recovery of hydrocarbons and clean sands (containing less than 0.1% of hydrocarbons) which are thus safe to be returned to the environment. In the case of petroleum bottom tank sludge, it was necessary to proceed with a double stage extraction with the addition of a wetting agent. A dosage of a Na2 Si O3 aqueous solution of 1% by weight has proven efficient, allowing an 82% recovery of hydrocarbons, with only 0.5% of hydrocarbons content in the solid residues.
Keywords:extraction  hot water extraction  petroleum sludge decontamination  tar sand extraction
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