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Miscibility and morphology of the poly(vinyl chloride)/styrene-acrylonitrile copolymer/poly(methyl methacrylate) ternary blend system
Authors:J. C. Huarng  Kyonsuku Min  James L. White
Abstract:The phase equilibrium of the ternary system poly (vinyl chloride) (PVC)/styrene-acrylonitrile copolymer (77/23) (SAN)/poly (methyl methacrylate) (PMMA) was investigated using a combination of turbidity, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC) measurements. Both turbidity and DSC were used to determine room temperature ternary phase diagrams. The results are basically similar, but the formulation based on the DSC results and the presumed phase model would seem more reliable since it is possible that immiscible blends may well have different phases with similar refractive indices.
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