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Synthesis of CuGeO3/reduced graphene oxide nanocomposite by hydrothermal reduction for high performance Li-ion battery anodes
Affiliation:1. Department of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung, Taiwan;2. Institute of Materials Science and Engineering, National Central University, Taoyuan, Taiwan;3. Department of Materials Science and Engineering, National Chiao Tung University, Hischu, Taiwan;1. Academy of Scientific and Innovative Research (AcSIR), India;2. CSIR-Central Electro Chemical Research Institute, Karaikudi, 630 003, Tamil Nadu, India;1. Department of Materials Science, Fudan University, Shanghai, 200433, PR China;2. Shanghai Innovation Institute for Materials, Shanghai, 200444, PR China;1. School of Materials Science and Engineering, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, Republic of Korea;2. Department of Energy Engineering Convergence, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, Republic of Korea
Abstract:Nowadays, Lithium-ion batteries (LIBs) are prevalently applied in numerous areas, leading to increasing demand of innovative electrodes with high specific capacities. An advanced CuGeO3/reduced graphene oxide (rGO) structure is designed and fabricated as the anode material taking the advantage of considerable capacity offered by CuGeO3 and stable framework constructed by rGO. The as-prepared CuGeO3 with 30 wt% GO addition exhibits the best electrochemical performance. Specifically, a reversible charge capacity of 909 mAh·g−1 with high coulombic efficiency of 91.49% at the current density of 100 mA g−1 after 200 cycles is demonstrated, and the rate capacity retains 747.6 mAh·g−1 with 91.59% capacity retention. These results indicate that the CuGeO3/rGO composite holds great potential in next-generation LIBs.
Keywords:Reduced graphene oxide  Nanocomposite  Anode material  Lithium-ion battery
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