Hot pressing sintering of zinc sulfide microsphere decorated with nanorods synthesized by the simple refluxing method |
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| Affiliation: | 1. Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China;2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;3. Key Laboratory of Bio-based Material Science & Technology (Northeast Forestry University), Ministry of Education, Harbin 150040, China;1. Tianjin Key Laboratory of TCM Chemistry and Analysis, Tianjin University of Traditional Chinese Medicine, Tianjin, 300193, PR China;2. Tianjin State Key Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, Tianjin, China;3. Business School, Beijing Wuzi University, Beijing, 101149, PR China;4. Analytical Instrumentation Centre, Tianjin University, Tianjin, 300072, PR China |
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| Abstract: | A zinc sulfide microsphere decorated with nanorods was synthesized using the refluxing method. Then, the as-obtained ZnS nanostructures were consolidated via the hot pressing (HP) technique. X-ray diffraction, Fourier transforms infrared spectroscopy, high-resolution transmission electron microscopy, field emission scanning electron microscopy (FESEM), diffuse reflectance spectroscopy, and X-ray mapping analyzes were used to characterize the ZnS sample. The effects of various factors such as pH, temperature, and reaction time were investigated on the morphology and particle size of ZnS nanostructures. The formation of sphalerite phase of ZnS nanoparticles was confirmed by the XRD analysis. FESEM also revealed that ZnS nanostructures with the molar ratio 1:1.3 (zinc: sulfur) had a spherical morphology decorated with sulfur nanorods. The ZnS nanostructures were consolidated by hot pressing technique at 860 °C for 2h under vacuum atmosphere. XRD analysis indicated that the sintered ceramic had a sphalerite phase. FESEM study demonstrated that ZnS ceramic had a grain size diameter within the range of 1–3 μm. |
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| Keywords: | Zinc sulfide Ceramics Hot pressing Refluxing method |
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