Modeling of naphtha reforming unit applying detailed description of kinetic in continuous catalytic regeneration process |
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Authors: | Davood Iranshahi Mohsen Karimi Shahram Amiri Mitra Jafari Razieh Rafiei Mohammad Reza Rahimpour |
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Affiliation: | 1. Dept. of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz 71345, Iran;2. Department of Chemical Engineering and Materials Science, University of California, Davis, 1 Shields Avenue, Davis, CA 95616, United States;3. Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran |
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Abstract: | Naphtha reforming is one of the most important processes in refineries in which high value-added reformate for gasoline pool and aromatics such as benzene, toluene, and xylene are produced. It is necessary to establish new naphtha reforming units and develop the traditional units to increase the efficiency of the processes. In this study, according to the recent progresses in the naphtha reforming technology, mathematical modeling of this process in continuous catalyst regeneration mode of operation is accomplished in two dimensions (radial and axial) by considering cross flow pattern. In addition, a new catalyst deactivation model has been proposed and a new reaction network model based on 32 pseudo-components with 84 reactions is investigated. Then, this model has been validated by comparing with industrial data, and its results have acceptable agreement. |
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Keywords: | Catalytic naphtha reforming process Continuous catalytic regeneration Two dimensional mathematical modeling Reaction network Catalyst deactivation model. |
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