| 新戊二醇磷酰氯的微波合成 |
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| 引用本文： | 赵晓涛,赵武利,李祖光,陆林光,王胜鹏.新戊二醇磷酰氯的微波合成[J].广东化工,2012,39(3):6-7,18. |
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| 作者姓名： | 赵晓涛 赵武利 李祖光 陆林光 王胜鹏 |
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| 作者单位： | 1. 浙江工业大学化学工程与材料学院,浙江杭州,310014
2. 浙江传化股份有限公司,浙江杭州,311215 |
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| 基金项目： | 浙江省科技厅钱江人才资助项目，浙江省重点创新团队资助项目 |
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| 摘 要： | 微波条件下合成新戊二醇磷酰氯，反应的最优条件是n（三氯氧磷）：n（新戊二醇）为1：1，反应溶剂为甲苯，V（甲苯）：m（新戊二醇）=20,微波功率为400W，反应时间为20min，产率达到91％．与常规相比明显缩短的反应时间，而且产率和常规一样（常规反应时间3h．产率90％）。
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| 关 键 词： | 阻燃剂 新戊二醇 三氯氧磷 微波 |
Synthesis of Neopentyl Glycol Chlorophosphate by Microwave Radiation |
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| Zhao Xiaotao,Zhao Wuli,Li Zuguang,Lu Linguang,Wang Shengpeng.Synthesis of Neopentyl Glycol Chlorophosphate by Microwave Radiation[J].Guangdong Chemical Industry,2012,39(3):6-7,18. |
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| Authors: | Zhao Xiaotao Zhao Wuli Li Zuguang Lu Linguang Wang Shengpeng |
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| Affiliation: | 1.College of Chemical Engineering and Materials Science,Zhejiang University of Technology,Hangzhou 310014; 2.Zhejiang Transfar Co.,Ltd.,Hangzhou 311215,China) |
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| Abstract: | Synthesis of neopentyl glycol chlorophosphate by microwave radiation,the optimal conditions of the reaction was n(POCl3)∶n(C5H12O2)=1∶1.The solvent is toluene,V(toluene)∶m(neopentylglycol)=20.The power of microwave was 400 W.The reaction time was 20 min,the rate of production was 91 %.Compared with conventional synthesis,the response time is short and the production rate is the same(conventional reaction time was 3 h,production rate 90 %). |
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| Keywords: | flame retardants neopentylglycol： phosphoms oxychloride： microwave |
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