| 纳米SiO2/环氧树脂/空心微珠反应动力学研究 |
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| 引用本文： | 惠雪梅,张炜,王晓洁,魏平.纳米SiO2/环氧树脂/空心微珠反应动力学研究[J].现代塑料加工应用,2005,17(6):4-7. |
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| 作者姓名： | 惠雪梅 张炜 王晓洁 魏平 |
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| 作者单位： | 1. 中国航天科技集团公司第四研究院43所,西安,710025
2. 第二炮兵工程学院101教研室,西安,710025 |
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| 摘 要： | 研究了纳米SiO2／环氧树脂／空心微珠体系的粘度特性，说明填料的加入对体系有一定的增粘作用。同时，采用示差扫描量热法（DSC）研究了纳米SiO2／环氧树脂／空心微珠体系的固化过程，利用不同升温速率下的DSC曲线求出三元体系的表观活化能、反应级数和频率因子等参数，得出了固化体系的反应动力学方程。
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| 关 键 词： | 示差扫描量热分析 纳米二氧化硅 空心微珠 环氧树脂 固化反应 动力学方程 |
| 收稿时间： | 2004-11-30 |
| 修稿时间： | 2005-07-05 |
STUDY ON THE KINETICS EQUATION OF CURING REACTION OF NANO-SiO2/EPOXY/HOLLOW MICROSPHERE COMPOSITE |
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| Hui Xuemei,Zhang Wei,Wang Xiaojie,Wei Ping.STUDY ON THE KINETICS EQUATION OF CURING REACTION OF NANO-SiO2/EPOXY/HOLLOW MICROSPHERE COMPOSITE[J].Modern Plastics Processing and Applications,2005,17(6):4-7. |
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| Authors: | Hui Xuemei Zhang Wei Wang Xiaojie Wei Ping |
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| Abstract: | The viscosity properties of nano-SiO2/epoxy/hollow microsphere composite were studied. The results showed that the fillers addition increased its viscosity certainly. Meanwhile, the curing reactions of nano-SiO2/epoxy/hollow microsphere composite were studied by DSC at different temperature raising rates. The apparent activation energy, reaction orders and frequency factor of the reaction were calculated based on the results of DSC curves. Finally the kinetics equation of the curing system was established. |
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| Keywords: | differential scanning calorimeter analysis nano-silicon oxide hollow microsphere epoxy resin curing reaction kinetics equation |
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