| Abstract: | The solubility of butane and isobutane in molten polypropylene (PP) and polystyrene (PS) was measured at pressures up to 3 MPa and along four isotherms from 438 to 483 K for PP and from 348 to 473 K for PS. The solubility increased with increasing pressure and decreasing temperature. At 438 K and 2 MPa, the solubilities of butane and isobutane in PP were 0.15 and 0.11 g‐gas/g‐polym, respectively. At 423 K and 2 MPa, the solubilities of butane and isobutane in PS were 0.08 and 0.05 g‐gas/g‐polym, respectively. Solubility could be correlated with the Sanchez‐Lacombe equation of state with temperature‐dependent binary interaction parameters to within 4.4% average relative deviation. Henry's constant for these gases in the PP and PS obtained in this work were used to determine correlation equations along with literature data. Polym. Eng. Sci. 44:2083–2089, 2004. © 2004 Society of Plastics Engineers. |
