Summary: The miscibility and crystallization behaviors of polyamide 6 (PA 6)/polytetrafluoroethylene (PTFE) blends, prepared via reactive extrusion, are systematically investigated by means of wide‐angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC), and dynamic mechanical thermal analysis (DMTA). WAXD measurements show that no co‐crystallization occurred between two components, while DSC and DMTA measurements suggest that a certain degree of miscibility between them might exist due to the formation of some copolymers during the reactive extrusion.
DMTA curves for the pure PA 6 sample and PA 6/PTFE blends with various compositions.