Ru-Na/C催化剂对4-（4＇-正丙基）环己基苯酚的催化反应

用NaOH处理Ru/C,制备了Ru-Na/C复合催化剂。评价结果表明：用Ru-Na/C催化剂,反应6小时后,4-（4＇-丙基）环己基苯酚（3PCO）苯环加氢的转化率为99.9%;4-（4＇-丙基）环己基环己基酮（3HHK）的选择性为80.4%,4-（4＇-丙基）环己基环己基醇（3HHE）的选择性为19.6%,较Ru/C催化剂的活性、转化率（82.0%）和选择性分别的4-（4＇-丙基）环己基环己基酮64.1%、4-（4＇-丙基）环己基环己基醇18.0%有显著提高。Ru-Na/C复合催化剂的良好催化活性和选择性是由于NaOH的添加及烘培过程改变了Ru/C催化剂的表面组成和结构并提高了Ru的还原能力。

The Catalytic Reaction of 4-(4-n-propyl)Cyclohexylphenol on Ru-Na/C Catalyst

The Ru-Na/C catalyst was prepared by improving Ru/C with NaOH. The evaluation indicated that the acitivity and selectivity of the catalyst were better than those of Ru/C catalyst since conrersion of 4-（4-n-propyl）cyclohexylphenol was 99.9% , the selectivity of 4-（4-n-propyl）cyclohexylcy- clohexanone was 80.4% and selectivity of 4-（4-n-propyl）cyclohexylcyclohexand was 19.6% after the six hours＇ reaction of Ru-Na/C catalyst .The preferable activity and selectivity of the catalyst were own to the addition of NaOH and the process of calcination in which the surface composing and structure of Ru/C catalyst were changed with the increase of deoxidize property of Ru.