Abstract: | Mono- and diquaternary ammonium cellulose anion exchangers in fabric form were prepared in nonaqueous media by reacting diethylaminoethyl (DEAE)-cotton with an alkyl halide, RX, or a dihaloalkane, X(CH2)nX, respectively. The alkyl group was varied from CH3 to C18H35, and n varied from 5 to 10 in the dihaloalkanes. Electron emission spectroscopy for chemical analyses (ESCA) showed that approximately 70% of the amino groups in the original DEAE-cotton were free amines. ESCA data showed that highest degree of quaternization of the free amine groups was obtained with CH3I but that diiodo and dibromo pentanes and decanes were also effective. Diquaternary ammonium cellulose exchangers of high nitrogen content had high wet and conditioned wrinkle recoveries, whereas the monoquaternary ammonium cellulose exchangers showed no improvement in wet or conditioned wrinkle recoveries. The monoquaternaries, like unmodified cottons and DEAE-cottons, were soluble in cupriethylenediamine hydroxide (cuene), and cross sections of their fibers expanded when subjected to layer expansion techniques. All diquaternaries were insoluble in cuene, and their cross sections did not layer. |