| BS－DMPT－CHP引发体系作用机制概述 |
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| 引用本文： | 莫清兰.BS－DMPT－CHP引发体系作用机制概述[J].化学与粘合,1994(3). |
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| 作者姓名： | 莫清兰 |
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| 作者单位： | 中国科学院广州化学研究所 |
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| 摘 要： | 本文概述了文献中关于厌氧胶引发体系的糖精－Ｎ，Ｎ－二甲，基－对－甲苯胺－异丙苯过氧化氢（ＢＳ－ＤＭＰＴ－ＣＨＰ）的作用机制．根据动力学研究结果说明厌氧胶的固化反应是氧化还原自由基聚合反应，而在氧化还原反应中的还原剂是ＢＳ－ＤＭＰＴ的电荷转移复合物，氧化剂应是厌氧胶体系中的微量氧，ＣＨＰ的氧化作用与ＢＳ－ＤＭＰＴ没有直接的联系．
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| 关 键 词： | 动力学，活化能，氧化还原反应，电荷转移复合物，作用机制 |
A Review on the Mechanism of BS-DMPT-CHR Initiation System |
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| Mo Qinglan.A Review on the Mechanism of BS-DMPT-CHR Initiation System[J].Chemistry and Adhesion,1994(3). |
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| Authors: | Mo Qinglan |
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| Abstract: | The mechanism of benzoic sulfimide-N, N-dimethyl-P-toluidinecumene hydroperoxide(BS DMPT-CHP ) for anaerobic adhesive initiation system in scientific literatures is reviewedExplained by the results of the kinetic studies,the care reaction of anaerobic adhesives proceedsby a redox initiated of radical polytherization, and the reducing agent of the redox reaction is thecharge transfer complex of BS-DMPT and the oxidizing agent may be the trace amounts of oxygenin site, but there is not direct relationship to the oxidization of CHP with BS-DMPT. |
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| Keywords: | kiretics activation enetgy redox reaction mechanism |
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