One-step through-mask electrodeposition of a porous structure composed of manganese oxide nanosheets with electrocatalytic activity for oxygen reduction |
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Authors: | Masaki Fukuda |
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Affiliation: | Department of Applied Chemistry, Yamaguchi University, 2-16-1 Tokiwadai, Ube 755-8611, Japan |
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Abstract: | Potentiostatic electrolysis of a mixed aqueous solution of Bu4NBr and MnSO4 at +1.0 V (vs. Ag/AgCl) on Pt electrode led to the oxidation of Br− and Mn2+ ions. X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and X-ray diffraction (XRD) revealed that this anodic process was followed by the deposition of insulating crystals of bromide salt of Bu4N+ and the subsequent formation of layered manganese oxide in the interstitial spaces of the bromide grains already grown. Dissolution of the bromide crystals in water left a well-dispersed porous texture composed of manganese oxide nanosheets. The resulting MnOx-modified electrode exhibited a larger catalytic current for the reduction of oxygen in alkaline solution, compared to the bare Pt electrode. |
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Keywords: | A Layered compounds Oxides C Atomic force microscopy X-ray diffraction D Electrochemical properties |
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