Azines from one-pot reaction of thiosemicarbazones |
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| Authors: | Ashraf A Aly Alaa A Hassan Alan B Brown Mahmoud A A Ibrahim El-Shimaa S M AbdAl-Latif |
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| Affiliation: | 1. Chemistry Department, Faculty of Science, Minia University, El-Minia, Egypt;2. Chemistry Department, Florida Institute of Technology, Melbourne, FL, USA |
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| Abstract: | Thermolysis and/or microwave irradiation of thiosemicarbazones gave the corresponding isothiocyanates, which on addition of either activated nitriles or aldehydes furnished various types of azines. The mechanism was discussed. The structures of products were proved by MS, IR, NMR, and elemental analyses. |
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| Keywords: | Thiosemicarbazones thermolysis microwave irradiation isothiocyanates azines |
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