Influence of Gd content on the structural,Raman spectroscopic and magnetic properties of CoFe2O4 nanoparticles synthesized by sol-gel route |
| |
Affiliation: | 1. Department of Physics, University of Rajshahi, Rajshahi, 6205, Bangladesh;2. Department of Physics, Rajshahi University of Engineering & Technology, Rajshahi, 6204, Bangladesh;3. Materials Science Division, Atomic Energy Center, Dhaka, 1000, Bangladesh |
| |
Abstract: | The structural and magnetic properties of sol-gel synthesized Gd doped (x = 0.00 to 0.15) CoFe2O4 nanoparticles (NPs) have been studied. The x-ray diffraction (XRD) and FTIR spectroscopy along with Raman spectra confirmed the formation of face centered cubic inverse spinel structure. TEM images showed the NPs are well-dispersed with average particle size 30 nm. Room temperature magnetic measurement showed the value of coercivity fluctuates from 353 Oe to 1060 Oe for different % of Gd content. The maximum coercivity, saturation magnetization, magnetic moment, magnetic anisotropy, remnant magnetization found for 0.03% Gd content are 1060.19 Oe, 77.53 emu/gm, 3.29 μ, 4.11 × 104 erg/cm3, 32.38 emu/gm, respectively. The large value of coercivity indicated that the interparticle interactions and crystalline anisotropy are high. Thus CoFe2-xGdxO4 magnetic NPs might be a potential candidate for data processing, automotive and telecommunications. |
| |
Keywords: | Nanoparticles Spinel ferrite Gd Sol-gel Raman spectra FC-ZFC |
本文献已被 ScienceDirect 等数据库收录! |
|