Densification of copper oxide doped alumina toughened zirconia by conventional sintering |
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Affiliation: | 1. Center of Advanced Manufacturing and Material Processing, Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia;2. Department of Mechanical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, Tungku Highway, Gadong, BE1410, Brunei Darussalam;3. Huanghe Jiaotong University, Zhengzhou, 454950, Henan Province, PR China;4. Tunku Abdul Rahman University College, Faculty of Engineering & Technology, Department of Mechanical Engineering, 53300, Kuala Lumpur, Malaysia;5. Centre for Innovative Construction Technology (CICT), Department of Civil Engineering, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia;6. Mechanical & Industrial Engineering Department, Qatar University, Doha, Qatar;7. Department of Biomedical and Chemical Engineering, University of Texas at San Antonio, Texas, USA |
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Abstract: | The effect of copper oxide doping (0.05–1 wt%) on the densification, microstructure evolution and mechanical characteristics of alumina toughened zirconia (ATZ: 80 wt% Y-TZP + 20 wt% Al2O3) ceramic composites was investigated. Green samples were pressureless sintered using a short hold time of 12 min at temperatures varying from 1250 °C to 1500 °C. The incorporation of up to 0.2 wt% copper oxide was beneficial in promoting densification at low sintering temperature and improving the mechanical properties of ATZ without affecting the tetragonal phase stability. It was found that 0.2 wt% copper oxide addition was most efficacious, and the samples could attain a relative density of approximately 92% at 1250 °C, approximately 97% dense at 1350 °C and above 99% dense at 1450–1500 °C. This approach was also accompanied by an improvement in the Vickers hardness (12.7 GPa) and fracture toughness (6.94 MPam1/2) when consolidated at 1450 °C/12 min. In comparison, the undoped composite exhibited relative densities of approximately 80% at 1250 °C, 87% at 1350 °C and approximately 97%–98% at 1450 °C-1500 °C. However, the study also found that higher dopant levels (0.5 wt% and 1 wt%) was not beneficial because the tetragonal zirconia phase was disrupted upon cooling from sintering, resulting in the monoclinic phase formation. In addition, low densification and poor mechanical properties were obtained. |
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Keywords: | Alumina-toughened zirconia ATZ Copper oxide Sintering additive Conventional sintering |
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