Ultrahigh electric breakdown strength,excellent dielectric energy storage density,and improved electrocaloric effect in Pb-free (1-x)Ba(Zr0.15Ti0.85)O3-xNaNbO3 ceramics |
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Affiliation: | 1. School of Materials and Energy, Southwest University, Chongqing, 400715, PR China;2. National and Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, School of Materials Science and Engineering, Shaanxi University of Technology, Shaanxi Hanzhong, 723001, PR China |
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Abstract: | In this study, NaNbO3 (NN) was introduced into Ba(Zr0.15Ti0.85)O3 (BZT) to form a solid solution with relaxor ferroelectric characteristics. The dielectric breakdown strength (BDS) of the specimen with 6 mol.% NN reached 680 kV/cm, the corresponding recoverable energy storage density (Wrec) was 5.15 J/cm3, and the energy storage efficiency (η) was 77%. The dissolution of Na + ions at the A position and Nb5+ ions at the B position of the perovskite structure reduced the concentration of oxygen vacancies in the lattice and compensated for defects. The doped ceramics exhibited lower dielectric loss and better thermal stability: the Wrec value was 2 ± 1% J/cm3 at 30–120 °C. In particular, in the 0.02NN ceramics, a ΔT of 1.81 K was achieved at 130 kV/cm, and the operating temperature zone expanded with the increase in doping concentration. The introduction of NN resulted in BZT ceramics that possess excellent energy storage performance and electrocaloric effect properties. |
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Keywords: | Barium titanate Relaxor ferroelectric Electrocaloric effect Energy storage Thermal stability |
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