Mechanochemical-hydrothermal synthesis and characterization of fluoridated hydroxyapatite |
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Authors: | Hui Gang Zhang Zhao Hui Xie |
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Affiliation: | Multiphase Reaction Laboratory, Institute of Process Engineering, Chinese Academy of Sciences, P.O. Box 353, Beijing 100080, China |
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Abstract: | Fluoridated hydroxyapatite (FHAp) was successfully synthesized from the starting materials of CaCO3, CaHPO4·2H2O, and CaF2 via a mechanochemical-hydrothermal route. X-ray diffraction, infrared spectroscopy, surface area measurements, and scanning electron microscopy identified the resultant powders as FHAp nanocrystals with the specific surface areas of up to 114.72 m2/g. The mechanism study revealed that under such mechanochemical-hydrothermal conditions the formation reactions of FHAp were completed in two stages. The starting materials firstly reacted into a poorly crystallized calcium-deficient apatite and the complete incorporation of fluoride ions into apatite occurred in the second stage. |
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Keywords: | A inorganic compounds B chemical synthesis |
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