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Preparation of VO2 nanowires and their electric characterization
Authors:Xingcai Wu  Yourong Tao  Zhihe Wang
Affiliation:a Laboratory of Mesoscopic Materials Science, State Key Laboratory of Coordination Chemistry and Department of Chemistry, Nanjing University, Nanjing 210093, PR China
b Department of Physics, Nanjing University, Nanjing 210093, PR China
Abstract:Large-scale VO2 nanowires have been synthesized by two-step method. First, we have been obtained (NH4)0.5V2O5 nanowire precursors by hydrothermal treatment of ammonium metavanadate solution at 170 °C. Secondly, the precursors have been sealed in quartz tube in vacuum and annealed to form VO2 nanowires at 570 °C. Scanning electron microscope and transmission electron microscope analysis show that the nanowires have self-assembling nanostructure with the diameter of about 80-200 nm, length up to125 μm. Electrical transport measurements show that it is semiconductor with conduction activate energy of 0.128 eV. A metal-semiconductor transition can be observed around 341 K.
Keywords:A  Nanostructures  C  X-ray diffraction  D  Electrical properties
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