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阿奇霉素废水的预处理
引用本文:杨文玲,董亚荣,王立栋,黄群贤,程建锋.阿奇霉素废水的预处理[J].化工进展,2009,28(7):1271.
作者姓名:杨文玲  董亚荣  王立栋  黄群贤  程建锋
作者单位:河北科技大学化学与制药工程学院,河北,石家庄,050018;河北科技大学环境科学与工程学院,河北,石家庄050018;中国环境管理干部学院人事处,河北,秦皇岛,066004
摘    要:针对阿奇霉素废水高COD、高氨氮浓度、高色度以及高含盐量的特点,采用吹脱-铁炭微电解-Fenton氧化预处理阿奇霉素废水,效果良好。试验结果表明:吹脱pH值为11~12、吹脱时间20 h时,氨氮去除率达到80%;铁炭微电解pH值为3~4、铁炭比为1.5、反应时间为80 min时,COD去除率达到45%;向微电解出水投加30 mL/L的H2O2(质量分数为30%)进行Fenton氧化处理,COD去除率提高到89.6%。预处理后,废水的BOD5/COD从0.18提高到0.3,提高了废水的可生化性。

关 键 词:阿奇霉素废水  Fenton氧化  吹脱  微电解

Pretreatment of azithromycin wastewater
YANG Wenling,DONG Yarong,WANG Lidong,HUANG Qunxian,CHENG Jianfeng.Pretreatment of azithromycin wastewater[J].Chemical Industry and Engineering Progress,2009,28(7):1271.
Authors:YANG Wenling  DONG Yarong  WANG Lidong  HUANG Qunxian  CHENG Jianfeng
Affiliation:School of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology;School of Environmental Science and Engineering,Hebei University of Science and Technology;Personnel Department,Environment Management College of China
Abstract:Air stripping–Fe-C microelectrolysis–Fenton oxidation process was used to treat the azithromycin waste water with characteristics of high COD,high ammonia,heavy color,as well as high salt content,and a good result was obtained. The experimental results indicated that the removal rate of the ammonia nitrogen reached 80% by air stripping when pH value was 11 to 12,stripping time was 20 h. When the reaction time for the microelectrolysis was 80 min and pH was 3 to 4,the removal rate of COD reached 45%. When the dosage of H2O2 (mass fraction 30%) to the microelectrolysis effluent was 30 mL/L,the removal rate of COD was increased to 89.6% by Fenton oxidation. After pretreatment of waste water,BOD5/COD was increased from 0.18 to 0.3,and the biodegradability of waste water was improved obviously.
Keywords:azithromycin waste water  Fenton oxidation  air stripping  microelectrolysis  
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