| 聚丙烯酸模板制备PAA/PbCrO_4复合纳米颗粒 |
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| 引用本文： | 郑雪琳,翁家宝,吕习周,孟东利,黄志彬. 聚丙烯酸模板制备PAA/PbCrO_4复合纳米颗粒[J]. 吉林化工学院学报, 2011, 28(1): 5-7 |
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| 作者姓名： | 郑雪琳 翁家宝 吕习周 孟东利 黄志彬 |
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| 作者单位： | 1. 福建师范大学,化学与材料学院,福建,福州,350007;福建省高分子材料重点实验室,福建,福州,350007
2. 福建师范大学,化学与材料学院,福建,福州,350007 |
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| 基金项目： | 国家自然科学基金资助项目,福建省自然科学基金资助项目,福建省教育厅资助项目 |
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| 摘 要： | 以低分子量聚丙烯酸(PAA)为高分子模板构建自组装体系,合成核-壳结构的PAA/PbCrO4纳米颗粒.通过TEM、XRD、FT-IR、UV-vis、荧光光谱等表征手段对产物的结构、形貌与光学性能进行研究.结果表明:PAA通过羧基与Pb2+的配位作用包覆在PbCrO4纳米颗粒表面,形成核-壳结构,内核PbCrO4尺寸为50~100 nm,为单斜晶系;外壳PAA层厚20 nm.与普通PbCrO4体相材料相比,产物在829~854 cm-1红外吸收峰变宽,紫外与荧光光谱产生了"蓝移",表现出纳米粒子所具有的特殊光学现象.
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| 关 键 词： | 聚丙烯酸 模板 铬酸铅 复合纳米颗粒 |
Fabrication of PAA/PbCrO_4 composite nanoparticles by PAA template method |
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| ZHENG Xue-Lin,WENG Jia-Bao,LV Xi-Zhou,MENG Dong-Li,HUANG Zhi-bin. Fabrication of PAA/PbCrO_4 composite nanoparticles by PAA template method[J]. Journal of Jilin Institute of Chemical Technology, 2011, 28(1): 5-7 |
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| Authors: | ZHENG Xue-Lin WENG Jia-Bao LV Xi-Zhou MENG Dong-Li HUANG Zhi-bin |
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| Affiliation: | ZHENG Xue-Lin1,2,WENG Jia-Bao1,LV Xi-Zhou1,MENG Dong-Li1,HUANG Zhi-bin1(1.College of Chemistry and Material Science,Fujian Normal University,Fuzhou 350007,China,2.Fujian Key Laboratory of Polymer Materials,China) |
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| Abstract: | PAA/PbCrO4 composite nanoparticles with core-shell structure were successfully synthesized by using polyacrylic acid as the template.The products were characterized by TEM,XRD,FT-IR,UV-vis and fluorescence spectroscopy.The results indicated that PAA was modified on the surface of PbCrO4 nanoparticles to form core-shell structure through the coordination between the carboxyl and Pb2+.The thickness of polymer shells was around 20nm and the PbCrO4 core was monoclinic structure with a grain size of 50~100nm.The... |
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| Keywords: | polyacrylic acid template PbCrO4 composite nanoparticle |
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