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纳米PbO和Bi2O3粉的制备及对推进剂燃烧性能的影响
引用本文:洪伟良,赵凤起,刘剑洪,田德余.纳米PbO和Bi2O3粉的制备及对推进剂燃烧性能的影响[J].火炸药学报,2001,24(3):7-9.
作者姓名:洪伟良  赵凤起  刘剑洪  田德余
作者单位:1. 深圳大学师范学院化生系,
2. 西安近代化学研究所,
摘    要:用Pd(NO3)2、Bi(NO3)3和NaOH为原料,通过室温固相反应,制备出纳米PbO和纳米Bi2O3粉末,用X-射线衍射仪和透射电镜对产物的组成、大小和形貌进行了表征,用纳米PbO和Bi2O3作燃速催化剂,在RDX-CMDB推进剂中进行了配方试验研究,实验结果表明,纳米Bi2O3能够提高推进剂的燃速,同时降低压强指数。

关 键 词:燃烧催化剂  纳米材料  氧化铅  三氧化二铋  硝胺改性双基推进剂
文章编号:1007-7812(2001)03-0007-03
修稿时间:2000年12月12

Synthesis of Nanometer PbO,Bi2O3 and Their Effect on Burning Properties of Solid Propellants
HONG Wei-liang,ZHAO Feng-qi,LIU Jian-hong,TIAN De-yu.Synthesis of Nanometer PbO,Bi2O3 and Their Effect on Burning Properties of Solid Propellants[J].Chinese Journal of Explosives & Propellants,2001,24(3):7-9.
Authors:HONG Wei-liang  ZHAO Feng-qi  LIU Jian-hong  TIAN De-yu
Abstract:Nanometer PbO and Nanometer Bi2O3 were synthesized by solid state reaction using Pb(NO3)2, Bi(NO3)3 with NaOH at room temperature. The crystal form, particle size and morphology of nanometer PbO and Bi2O3 were characterized by XRD and TEM. The effect of two nanometer catalysts on burning Properties of RDX-CMDB propellant were investigated. The results show that nanometer Bi2O3 can increase the burning rates of the propellant and lower burning rate pressure exponent.
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