| 侧链含PEO链段的苯胺共聚物的合成与表征 |
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| 引用本文： | 柳娜,官建国. 侧链含PEO链段的苯胺共聚物的合成与表征[J]. 武汉理工大学学报, 2003, 25(3): 1-3,39 |
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| 作者姓名： | 柳娜 官建国 |
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| 作者单位： | 武汉理工大学 |
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| 基金项目： | 国家自然科学基金资助 (2 990 40 0 5 ) |
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| 摘 要： | 采用化学氧化法将苯胺（An)与间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯（MPAE）进行共聚，制备出一种侧链含聚氧化乙烯（PEO）键段的苯胺共聚物。结果表明，MPAE投料量增加，共聚产率线性减少，共聚物的热稳定性逐渐下降，在极性有机溶剂中的溶解及成膜性能提高，但MPAE摩尔投料量达30%后，产物溶解性无明显变化。
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| 关 键 词： | 苯胺 聚氧化乙烯 共聚物 制备 表征 |
| 文章编号： | 1671-4431(2003)03-0001-03 |
Preparation and Characterization of a Copolymer Based on Aniline Containing PEO Segments on the Side Chain |
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| Liu Na Guan Jianguo. Preparation and Characterization of a Copolymer Based on Aniline Containing PEO Segments on the Side Chain[J]. Journal of Wuhan University of Technology, 2003, 25(3): 1-3,39 |
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| Authors: | Liu Na Guan Jianguo |
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| Affiliation: | Liu Na Guan Jianguo |
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| Abstract: | A copolymer containing PEO segments on the side chain was synthesized by chemical oxidation copolymerization of aniline and its derivative m-phenylene diamino formyl alkylenediamine poly(ethyleneoxy) acetate(MPAE). The results showed that the yield of the copolymers and their thermal stability declined with increasing of MPAE feed content, the solubility of the copolymers in polar organic solvents and their ability to form membrane enhanced, but further enhancement could not be observed when the ratio of MPAE to the total monomers is more than 30%. |
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| Keywords: | polyaniline polyethylene oxide copolymer preparation characterization |
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