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A-CaCO3及HDPE-g-MAH对HDPE复合材料性能的影响
引用本文:施燕琴,陈思,方晶,董玉欣,卜扬帆,王旭. A-CaCO3及HDPE-g-MAH对HDPE复合材料性能的影响[J]. 塑料工业, 2012, 40(6): 80-83
作者姓名:施燕琴  陈思  方晶  董玉欣  卜扬帆  王旭
作者单位:浙江工业大学化学工程与材料学院,浙江杭州,310014
基金项目:国家自然科学基金,浙江工业大学校基金,省科技厅(创新团队)支持项目
摘    要:采用熔融混炼法制备了活性碳酸钙(A-CaCO3)填充高密度聚乙烯(HDPE)复合材料。研究了A-CaCO3和马来酸酐接枝HDPE(HDPE-g-MAH)对复合材料力学性能、结晶性能的影响;并采用SEM对复合材料的微观形貌进行了观察。研究结果表明:A-CaCO3对HDPE/A-CaCO3复合材料的拉伸强度和弯曲强度影响不大,但能提高复合材料的冲击强度和结晶度;HDPE-g-MAH的加入能够显著改善A-CaCO3与基体HDPE之间的界面相容性,提高HDPE/HDPE-g-MAH/A-CaCO3复合材料的拉伸强度和结晶度,但降低了复合材料的冲击强度。

关 键 词:高密度聚乙烯  活性碳酸钙  力学性能  结晶性能  相容剂

Influence of A-CaCO3 and HDPE-g-MAH on the Properties of HDPE Composites
SHI Yan-qin , CHEN Si , FANG Jing , DONG Yu-xin , BU Yang-fan , WANG Xu. Influence of A-CaCO3 and HDPE-g-MAH on the Properties of HDPE Composites[J]. China Plastics Industry, 2012, 40(6): 80-83
Authors:SHI Yan-qin    CHEN Si    FANG Jing    DONG Yu-xin    BU Yang-fan    WANG Xu
Affiliation:(Institute of Chemical Engineering and Materials,Zhejiang University of Technology,Hangzhou 310014,China)
Abstract:HDPE filled A-CaCO3 composites were prepared by melt compounding method.The effect of A-CaCO3 and HDPE-g-MAH on mechanical properties,crystal property of the composites was studied.The microstructure of the composites was observed by SEM.The result showed that A-CaCO3 had little effect on the tensile strength and flexural strength,but enhanced impact strength and crystal degree of the composites.The compatibility between HDPE and A-CaCO3,tensile strength and crystal degree of the composites were improved by adding HDPE-g-MAH,but impact strength was decreased.
Keywords:HDPE  A-CaCO3  Mechanical Property  Crystal Property  Compatibilizer
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