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超临界CO2制备NaCl/PS微孔泡沫复合材料
引用本文:戢菁,李湖燕,张海琛,廖霞.超临界CO2制备NaCl/PS微孔泡沫复合材料[J].塑料工业,2012,40(7):100-103,34.
作者姓名:戢菁  李湖燕  张海琛  廖霞
作者单位:四川大学高分子科学与工程学院,四川成都,610065
摘    要:利用超临界流体发泡技术制备了氯化钠(NaCl)颗粒填充聚苯乙烯(PS)的微孔泡沫复合材料。通过扫描电子显微镜(SEM)观察了材料的断面形态,并分析了氯化钠的粒径、含量及超临界CO2的饱和温度对微孔泡沫复合材料的泡孔形态的影响。结果表明:含有NaCl颗粒的微孔PS泡沫与纯PS泡沫在泡孔的形状和泡孔的尺寸等方面有所不同,纯PS微孔泡沫材料的泡孔分布较均匀、形状呈椭圆形,而添加了NaCl的PS微孔泡沫出现了大、小泡孔并存的泡孔结构。

关 键 词:聚合物泡沫  聚苯乙烯  超临界二氧化碳  微孔材料  形态

Preparation of Microcellular NaCl/PS Composite with Supercritical CO2
JI Jing , LI Hu-yan , ZHANG Hai-chen , LIAO Xia.Preparation of Microcellular NaCl/PS Composite with Supercritical CO2[J].China Plastics Industry,2012,40(7):100-103,34.
Authors:JI Jing  LI Hu-yan  ZHANG Hai-chen  LIAO Xia
Affiliation:(College of Polymer Science & Engineering,Sichuan University,Chengdu 610065,China)
Abstract:NaCl particles filled PS microcellular foaming composite material was prepared by supercritical fluid foaming technology.The fracture surface of NaCl/PS was observed through SEM.The effects of particle size,content and saturation temperature of supercritical CO2 on the cell morphology of the microcellular foams were investigated.The results showed that the microcellular PS foams of NaCl exhibited pore morphology with two different sizes which was different from the pure PS.Pure PS microporous foam was more uniform distributed,the shape was oval,and the PS micro-cell foam with NaCl had coexistence of large and small foam cell structure.
Keywords:Polymer Foam  PS  Supercritical CO2  Microcellular Materials  Morphology
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