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Influence of pigment properties on UV‐curing efficiency
Authors:Lavinia Macarie  Gheorghe Ilia
Affiliation:1. Institute of Chemistry Timisoara of Romanian Academy, 300223 Timisoara, Romania;2. Faculty of Chemistry, Biology and Geography, West University, 300115 Timisoara, Romania
Abstract:The curable formulations containing monomer‐diacrylate, photoinitiator‐p‐methoxybenzoyldiphenylphosphine oxide/benzyldimethylketal, additive reactive‐triethylamine, and inorganic thermoresistant pigments‐white, red, green, and blue were cured by UV exposure films. A series of experiments was carried out to investigate the relationship between the particle size distribution of the inorganic pigment and the colorimetric and mechanical properties of the UV acrylic curable coatings. Pendulum hardness and appearance of the films depend on the content and particle size distribution of the pigment. Optimal particle size distribution and pigment content were established to obtain the best films concerning their pendulum hardness and chromatic parameters. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 247–252, 2007
Keywords:UV curable formulation  pigmented coatings  photoinitiators  film properties
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