Catalytic hydrogenation of nitrile rubber using palladium and ruthenium complexes |
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| Authors: | Gracélie A. S. Schulz Edson Comin Roberto F. de Souza |
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| Affiliation: | Institute of Chemistry, Universidade Federal do Rio Grande do Sul, Porto Alegre 91501‐970 RS, Brazil |
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| Abstract: | The catalytic hydrogenation of acrylonitrile‐butadiene copolymer (nitrile rubber, NBR) using Pd(OAc)2 or RuCl2(PPh3)3 catalysts has been investigated in order to produce a totally saturated nitrile rubber. The hydrogenation of NBR is effective with both catalysts and achieved total conversion under the appropriate reaction conditions. In the case of palladium the effects of reaction parameters such as reaction temperature, pressure, time, catalyst concentration, and NBR concentration have been investigated. Even though both ruthenium‐ and palladium‐based catalysts are effective in the production of HNBR, the former requires harsh reaction conditions and has the drawback of gel formation under high conversion, motivating the migration to RuCl2 (PPh3)3 as an alternative catalyst. The degree of hydrogenation was determined by IR and NMR spectroscopy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 |
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| Keywords: | hydrogenation nitrile rubber catalysis palladium acetate catalyst dichlorotris(triphenyl)phosphine ruthenium catalyst characterization of rubber |
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