Phenol–formaldehyde–pyrolytic oil resins for wood preservation: A rheological study |
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| Authors: | Daniel Mourant Bernard Riedl Denis Rodrigue Dian‐Quing Yang Christian Roy |
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| Affiliation: | 1. Département de Génie Chimique, Université Laval, Québec, Canada;2. Département des Sciences du Bois et de la Forêt, Université Laval, Québec, Canada;3. Email:dian‐qing.yang@qc.forintek. ca;6. Forintek Canada Corp, Québec, Canada;7. Vaperma, Saint‐Romuald, Québec, Canada |
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| Abstract: | The rheological properties of a phenol–formaldehyde resin containing various ratios of softwood pyrolytic oil as phenol substitute were investigated using the simple Bingham rheological model for viscoplastic fluids. Flow activation energy was determined for the various resin blends and the pyrolytic oil between room temperature and 50°C and correlations relating the flow activation energy to the weight fraction of pyrolytic oil in the resin are proposed. Apparent crosslinking activation energy with and without copper chloride used as an activator was also evaluated based on two gel time measurements between 75 and 105°C. A significant decrease in activation energy was observed for the phenol–formaldehyde resin cured with copper chloride, while the effect was less important for resins containing pyrolytic oil even when gel times were much shorter for PF‐resins. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 |
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| Keywords: | pyrolytic oil phenol– formaldehyde resin rheology copper chloride activation energy |
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