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煤液化油的基本热力学性质测定方法的分析
引用本文:王迎春 凌开成 申峻 盛清涛. 煤液化油的基本热力学性质测定方法的分析[J]. 煤炭转化, 2005, 28(4): 74-78
作者姓名:王迎春 凌开成 申峻 盛清涛
作者单位:太原理工大学化工学院 030024太原硕士生(王迎春),太原理工大学化工学院 030024太原教授、博士生导师(凌开成),太原理工大学化工学院 030024太原博士、副教授(申峻),太原理工大学化工学院 030024太原硕士(盛清涛)
基金项目:国家重点基础研究发展计划项目(2004CB217602).
摘    要:分析了煤液化油的一些基本热力学性质:比热、蒸汽压、气-液相平衡常数和蒸发焓等,并参考石油基本热力学性质的各种测定方法及关联式计算法,探索研究了煤液化油基本热力学性质的测定方法和关联式计算法,特别是对煤液化油比热、蒸汽压的测定、气-液相平衡常数的计算及蒸发焓的估算作了详尽的讨论.最后得出了测定煤液化油这些热力学性质的适宜方法.简要概括了煤液化油馏分临界性质参数的计算.

关 键 词:煤液化油  热力学性质  蒸汽压  气-液相平衡常数
收稿时间:2005-05-17
修稿时间:2005-07-30

ANALYSIS OF MEASURING METHODS OF BASIC THERMODYNAMIC PROPERTIES OF COAL LIQUEFIED OIL
Wang Yingchun, Ling Kaicheng ,Shen Jun , Sheng Qingtao. ANALYSIS OF MEASURING METHODS OF BASIC THERMODYNAMIC PROPERTIES OF COAL LIQUEFIED OIL[J]. Coal Conversion, 2005, 28(4): 74-78
Authors:Wang Yingchun   Ling Kaicheng   Shen Jun    Sheng Qingtao
Affiliation:College of Chemical Engineering and Technology,Taiyuan University of Technology, 030024 Taiyuan
Abstract:Basic thermodynamic properties of coal liquefied oil were analyzed, with measuring methods and some correlations about basic thermodynamic properties of petroleum, measuring methods and correlations about basic thermodynamic properties of coal liquefied oil were studied.The measurement of vapor pressure, calculating of vapor-liquid phase equilibrium constant and appraising calculating process of vaporization enthalpy of coal liquefied oil were detailedly discussed. Finally, the best way of measuring these properties was obtained. In addition, appraising calculating of critical properties of coal liquefied oil fractions were simply outlined.
Keywords:coal liquefied oil  thermodynamic properties  vapor pressure  vaporization enthalpy
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