Polyoxometalate Supported Cinchona-Derived Chiral Amine for Asymmetric Organocatalysed Aldol Reaction |
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Authors: | Qiu Chen Cui Xin Lan-Lan Lou Kai Yu Fei Ding Shuangxi Liu |
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Affiliation: | 1. Institute of New Catalytic Materials Science and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China
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Abstract: | A heterogeneous polyoxometalate-based organocatalyst of cinchona-derived chiral amine that is supported on polyoxometalate was synthesized by a simple acid–base strategy for the asymmetric Aldol reaction. The organic–inorganic polyoxometalate catalyst could be easily recycled by filtration and reused four-times with only a slight change of enantioselectivity. |
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