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Pilot-Scale Operation of a Concrete Sludge Recycling Plant and Simultaneous Production of Calcium Carbonate
Authors:Atsushi Iizuka  Takeshi Sasaki  Masato Honma  Hiroyuki Yoshida  Yasuyuki Hayakawa  Yukio Yanagisawa
Affiliation:1. Research Center for Sustainable Science and Engineering, Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi, Japan;2. Nippon Concrete Industries, Co. Ltd., Minato-ku, Tokyo, Japan;3. Department of Environment Systems, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa, Chiba, Japan
Abstract:A pilot-scale plant to treat concrete sludge and produce calcium carbonate (CaCO3) and an environmental purification agent (phosphorus adsorbent derived from concrete sludge, PAdeCS®) was designed, constructed, and operated. Concrete sludge from a concrete pile and pole production plant, boiler gas containing CO2, and groundwater were used in the plant. The process involved calcium extraction from concrete sludge into water, followed by reaction of the calcium with CO2 to produce crystalline CaCO3. The pilot-scale plant was operated for 1 week, and the mass flows, conversion of CO2 to CaCO3, and net CO2 emissions of the process were estimated. High-purity CaCO3 (>97%) suitable for industrial use was obtained. Based on the power consumption of the process and the amount of CO2 sequestered into CaCO3, a net reduction in CO2 emissions can be achieved using this process. The produced PAdeCS can be used as an inexpensive substitute for calcium series environmental purification agents.
Keywords:Calcium carbonate  Carbon dioxide  CO2 utilization  Concrete sludge  Mineral carbonation  Waste treatment
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