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表层沉积物中粘土及其主要组分吸附Cu和Zn的行为研究
引用本文:李鱼,高茜,李鸿业,王晓丽,王婷,王燕萍.表层沉积物中粘土及其主要组分吸附Cu和Zn的行为研究[J].华北电力大学学报,2009,36(2).
作者姓名:李鱼  高茜  李鸿业  王晓丽  王婷  王燕萍
作者单位:1. 华北电力大学能源与环境研究中心,北京,102206;吉林大学环境与资源学院,吉林,长春,130023
2. 华北电力大学能源与环境研究中心,北京,102206
3. 吉林大学环境与资源学院,吉林,长春,130023
基金项目:国家重点基础研究发展规划(973计划) 
摘    要:以表层沉积物中的粘土为研究对象,利用选择性萃取分离-吸附-加和模型方法考察了粘土及主要组分(铁锰氧化物、有机质和粘土矿物)吸附Cu,Zn的热力学特性。结果表明粘土吸附Cu,Zn的能力略高于表层沉积物吸附Cu,Zn的能力,且粘土中铁锰氧化物对Cu,Zn吸附的相对贡献最大,有机质次之,粘土矿物最小,与表层沉积物中各组分吸附Cu,Zn的规律一致,说明铁锰氧化物控制水环境中痕量重金属的作用不容忽视。

关 键 词:表层沉积物  粘土  铁氧化物      吸附

Study of Cu and Zn adsorption on the clay and its main components in surficial sediments
LI Yu,GAO Qian,LI Hong-ye,WANG Xiao-li,WANG Ting,WANG Yan-ping.Study of Cu and Zn adsorption on the clay and its main components in surficial sediments[J].Journal of North China Electric Power University,2009,36(2).
Authors:LI Yu  GAO Qian  LI Hong-ye  WANG Xiao-li  WANG Ting  WANG Yan-ping
Affiliation:1.Energy and Environmental Research Center;North China Electric Power University;Beijing 102206;China;2.College of Environment and Resources;Jilin University;Changchun 130023;China
Abstract:Selective chemical extraction-adsorption-additivity model was employed to analyze thermodynamic characteristics of Cu and Zn on the clay and its main components(Fe/Mn oxides,organic materials and clay minerals) in surficial sediments.The results show that the adsorption ability of clay towards Cu and Zn is much stronger than those of surficial sediments,and the most contribution was attributed to Fe oxides in the clay for Cu and Zn adsorption,next to OMs,and with the least from clay minerals.The resulted in...
Keywords:surficial sediments  clay  Fe oxides  Cu  Zn  adsorption  
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