Liquid crystallinity in trimer oligomers isolated from petroleum and pyrene pitches |
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| Affiliation: | 1. Department of Chemical and Biomolecular Engineering, Center for Advanced Engineering Fibers and Films, Clemson University, Clemson, SC 29634-0909, USA;2. Air Force Research Laboratory, AFRL/RQRC, 10 E. Saturn Blvd. Edwards, CA 93524-7680, USA;1. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;2. Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan;1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, Shandong 266580, People’s Republic of China;2. China National Offshore Oil Corporation, Beijing 100010, People’s Republic of China;3. Institute of Applied Ecology, Chinese Academy of Sciences, People’s Republic of China;4. Sinopec Zhenhai Refining & Chemical Company, Zhenhai 315200, People’s Republic of China;1. State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing, 100029, China;2. Beijing Key Laboratory of Space Thermal Control Technology, China Academy of Space Technology, No.104 Youyi Road, Haidian, Beijing, China |
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| Abstract: | The first unsubstituted, monodisperse polycyclic aromatic hydrocarbon (PAH) to form a liquid crystalline phase (100% mesophase) has been isolated. With a molecular weight of 598 Da and consisting of only 14 aromatic rings, this pyrene trimer is also the lowest molecular weight (mol wt) PAH species for which the existence of liquid crystallinity has been reported. Multiple isomers of the pyrene trimer exist, providing the melting-point depression (mpt = 290 °C) necessary for the existence of a liquid phase and the possibility of mesophase formation. The trimer cut of M-50 pitch (mol wt = 645–890 Da; mpt = 330 °C) has also been isolated and was found to consist of ∼40% mesophase. This trimer is the lowest average mol wt carbonaceous pitch for which significant mesophase formation has been reported. Both trimers were isolated from their starting pitches via packed-column supercritical extraction, using toluene and N-methylpyrrolidone (NMP) mixtures as the extractive solvent. Mass spectrometry and UV–vis and fluorescence spectroscopy were used for molecular characterization. The results of this study indicate that for PAHs, the molecular weight for which liquid crystallinity occurs can be significantly reduced by creating PAH oligomers with lower polydispersity and increased monomer-unit homogeneity. |
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