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Tungsten oxide nanowire-reduced graphene oxide aerogel for high-efficiency visible light photocatalysis
Affiliation:1. Department of Science and Technology, Linköpings Universitet, SE-60174 Norrköping, Sweden;2. Innventia AB, Box 5604, SE-114 86 Stockholm, Sweden;3. Materials Research Centre, Indian Institute of Science, Bangalore 560012, India;1. School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;2. Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China;1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China;2. Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, PR China;1. School of Electrical and Electronic Engineering, Tianjin Key Laboratory of Film Electronic & Communication Devices, Tianjin University of Technology, Tianjin 300384, China;2. School of Materials Science and Engineering, Tianjin Key Lab for Photoelectric Materials & Devices, Tianjin University of Technology, Tianjin 300384, China;3. Singapore Institute of Manufacturing Technology, Agency for Science, Technology and Research (A*STAR), 71 Nanyang Drive, 638075, Singapore;1. College of Environmental Science and Engineering, Hunan University, Changsha, 410082, China;2. Key Laboratory of Environment Biology and Pollution Control, Hunan University, Ministry of Education, Changsha, 410082, China
Abstract:A light, 3-D, porous aerogel was fabricated by way of a simple approach from 1-D tungsten oxide nanowires and 2-D reduced graphene oxide sheets. The as-prepared graphene oxide, tungsten oxide nanowires, and tungsten oxide-reduced graphene oxide (W18O49-RGO) aerogel were characterised. The photocatalytic activities of as-prepared aerogel under visible light irradiation were investigated through the degradation of six different organic dyes including Rhodamine B, reactive black 39, reactive yellow 145, weak acid black BR, methyl orange, and weak acid yellow G. In comparison with the pure W18O49 nanowires, the prepared W18O49-RGO aerogel had significantly improved photocatalytic efficiency. Also, the photocatalysis of W18O49-RGO aerogel maintained its efficiency after 30 cycles for each of the six dyes. The photocatalytic mechanism was studied by adding hole and radical scavengers: the results confirmed that the holes generated in W18O49-RGO aerogel played a key role in the visible light photocatalytic process.
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