| 三芳基硫鎓盐的合成及光引发阳离子聚合反应 |
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| 引用本文： | 徐俊伟,陈德铨,史素青,聂俊. 三芳基硫鎓盐的合成及光引发阳离子聚合反应[J]. 信息记录材料, 2006, 7(1): 34-37 |
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| 作者姓名： | 徐俊伟 陈德铨 史素青 聂俊 |
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| 作者单位： | 1. 常州华钛化学有限公司,常州,213241
2. 北京化工大学,材料科学工程学院,北京,100029 |
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| 摘 要： | 采用实时红外光谱仪(R I—FTIR)对阳离子光引发剂UVI—6992和UVI—6976与4种环氧单体的光聚合动力学进行了研究,对部分固化膜性能进行了测定。结果表明,引发剂浓度从0.5wt%增加到2wt%时,光聚合速率迅速增加,当光引发剂UVI—6992浓度为3wt%时,4种环氧单体轩化率增增长顺序为K126
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| 关 键 词： | 光聚合 阴离子光引发剂 环氧单体 膜性能 |
| 文章编号： | 1009-5624-（2006）01-0034-04 |
| 收稿时间： | 2005-08-03 |
| 修稿时间： | 2005-08-03 |
Synthesis of Triarylsulfonium Salts and Cationic Plotopolymerization |
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| XU Jun-wei,CHEN De-quan,SHI Su-qing,NIE Jun. Synthesis of Triarylsulfonium Salts and Cationic Plotopolymerization[J]. Information Recording Materials, 2006, 7(1): 34-37 |
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| Authors: | XU Jun-wei CHEN De-quan SHI Su-qing NIE Jun |
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| Affiliation: | 1. Runtec Cheminal CO. Ltd. , Changzhou 213241, China; 2. College of Material Science and Engiering, Beijing University of Chemicd Technology, Beijing 100029, China |
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| Abstract: | The kinetics of cationic photo-polymerization of epoxide-based monomers has been studied by real-time infrared spectroscopy(QT-FTIR) and some properties of cured films are measured.The results show that with the increase of initiator concentration from 0.5% to 2%,the rate of photo-polymerization increases dramatically.At the fixed photo-initiator(UVI-6992) concentration,the rate of polymerization increases at following order for four epoxy monomers K126
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| Keywords: | photo-polymerization cationic photo-initiator |
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