B3O4(OH) · 0.5(C4H10N2): First organic–inorganic hybrid borate with a neutral layered framework |
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| Affiliation: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China;2. University of Chinese Academy of Sciences, Beijing 100039, PR China;1. Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, PR China;2. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin 541004, PR China;3. Department of Physics and CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal;1. Department of Crystallography, Faculty of Geology, Lomonosov Moscow State University, Moscow, Leninskije Gory 1, 119992 GSP-2, Russia;2. Laboratory of Functional Materials, Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Leninskije Gory 1, 119992 GSP-2, Russia;3. Laboratory of Fourier Spectroscopy, Institute of Spectroscopy of Russian Academy of Science, Troitsk, Fizicheskaja 5, Moscow, 142191, Russia;1. Department of Crystallography, Faculty of Geology, Lomonosov Moscow State University, Moscow, Leninskije Gory 1, 119992, GSP-2, Russia;2. Laboratory of Functional Materials, Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Leninskije Gory 1, 119992, GSP-2, Russia |
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| Abstract: | A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions. |
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