A trinuclear anionic trifluoroacetato derivative of iron(II) containing a central O(–I) ligand |
| |
| Affiliation: | 1. Department of Chemistry, California State University, Sacramento, 6000 J Street, Sacramento, CA 95819, USA;2. Department of Chemistry, University of California, Davis, One Shields Ave., Davis, CA 95616, USA;1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China;2. Graduate University of Chinese Academy of Sciences, Beijing 100039, PR China;3. School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, PR China |
| |
| Abstract: | The reaction of Fe(CO)5 with CF3COOH/(CF3CO)2O, or with CF3COOH, in DMF at about 140 °C produces the colourless compound 1, Fe(DMF)6]Fe3(μ3-O) (CF3COO)6(DMF)3]2, constituted by the Fe(DMF)6]2+ cation and by two Fe3(μ3-O)(μ2-CF3COO)6(DMF)3]? anions, with a triangular disposition of the three iron atoms, the central substantially coplanar oxygen atom being formulated as a singly charged anion O(–I) stabilized by complexation to iron(II). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
