First hexanuclear manganese(II) μ6-Cl centered carboxylate anion: Synthesis,structure and magnetic properties |
| |
| Affiliation: | 1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, 119991 Moscow, GSP-1, Russian Federation;2. International Tomography Centre, Siberian Branch, Russian Academy of Sciences, Institutskaya str. 3a, 630090 Novosibirsk, Russian Federation;1. Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata 700 032, India;2. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany;3. Departamento de Química, Universitat de les Illes Balears, Crta. deValldemossa km 7.5, 07122 Palma, Baleares, Spain;1. N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky Prosp. 31, 119991 GSP-1 Moscow, Russian Federation;2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina 4, 119991 Moscow, Russian Federation;3. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russian Federation;4. L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03028 Kiev, Ukraine |
| |
| Abstract: | Reaction of manganese(II) polymer Mn5Cl(OH)(Piv)8(MeCN)(HPiv)(H2O)]n (1, HPiv is pivalic acid) and 2-benzoylpyridine (L) in MeCN produces the ionic complex Mn3(Piv)5L2(MeCN)]+Mn6Cl(Piv)12]? · MeCN (3) containing the unusual hexanuclear {Mn6(μ6-Cl)} anion. An analogous anion was also observed in the complex Mn6Cl(Piv)12]?(NEt4)+ · 5MeCN (4) prepared by the reaction of the polymer Mn(Piv)2(EtOH)]n (2) with NEt4Cl in MeCN. Complexes 3 and 4 were characterized by the X-ray diffraction and magnetic susceptibility. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
