A novel 3D twofold interpenetrating microporous metal-organic framework containing 1D water tapes with cyclic pentamer units |
| |
| Affiliation: | 1. School of Materials Science and Engineering, Nanjing Tech University, No.5 Xinmofan Road, Nanjing 210009, Jiangsu, China;2. School of Materials Science and Engineering, Xi''an University of Technology, No.5 South Jinhua Road, Xi''an 710048, Shanxi, China;1. College of Chemistry, Sichuan University, Chengdu 610064, PR China;2. Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, PR China;1. Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;2. University of the Chinese Academy of Sciences, Beijing 100049, China;1. School of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, Jiangsu 215500, China;2. School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221000, China |
| |
| Abstract: | The self-assembly of Cu2+ ions with malate and 1,3-bis(4-pyridyl)propane (bpp) affords a 3D coordination polymer {Cu(Hmal)(bpp) · 6H2O]}n (1) (malic acid = H3mal). The metal ions were interconnected by α- and β-carboxylate of malate produce infinite Cu(C4H4O5)]n layers, which were further pillared by bridging ligand bpp molecules to form a 3D interpenetrating network. Of further interest, lattice water molecules form 1D infinite water tapes in 1D open cavities. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
