Blue-green photoluminescent 5- and 10-connected metal 5-(4′-carboxy-phenyl)tetrazolate coordination polymers |
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| Affiliation: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, PR China;2. Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China;3. Hubei Normal University, Institute for Advanced Materials, Cihu Road, Huangshi, PR China;1. College of Science, Nanjing Forestry University, Nanjing, Jiangsu 210000, People''s Republic of China;2. Zhengzhou Tobacco Research Institute of China National Tobacco Corporation, Zhengzhou, Henan 450001, People''s Republic of China |
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| Abstract: | Hydrothermal reaction of Zn/Cd salts, NaN3 and 4-cyanobenzoic acid via in situ [2 + 3] cycloaddition generated two blue-green photoluminescent coordination polymers [Zn(cptta)(H2O)] (1) and [Cd(cptta)(H2O)] (2) (H2cptta = 5-(4′-carboxy-phenyl)tetrazole). When only metal ions are considered as nodes, 1 shows rare 5-connected Shubnikov plane topological type and 2 has unprecedented 10-connected {312.424.59} topological type. |
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