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Construction of two-dimensional supramolecular structure containing water tetramer and octamer
Affiliation:1. Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China;2. School of Resource and Civil Engineering, Northeastern University, Shenyang 110004, China;1. National Key Laboratory of Science and Technology on Micro/Nano Fabrication, Shanghai Jiao Tong University, Shanghai 200240, China;2. Key Laboratory for Thin Film and Microfabrication of Ministry of Education, Department of Micro/Nano-electronics, Shanghai Jiao Tong University, Shanghai 200240, China;3. Key Laboratory of Functional Molecular Solids of the Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China;1. Department of Chemistry, Sri Venkateswara University, Tirupati 517 502, India;2. Department of Chemistry, Sri Venkateswara College of Engineering, Tirupati 517 507, India;1. OIE Reference Lab for Swine Streptococcosis, Nanjing 210095, China;2. Key Lab of Animal Bacteriology, Ministry of Agriculture, Nanjing Agricultural University, Nanjing 210095, China
Abstract:The complex Cd2(phen)4(p-phth)(H2O)2](p-phth) · 10H2O (1) has been synthesized by the reaction Cd(NO3)2 with phen and p-phth (where phen = 1,10-phenanthroline, p-phth = p-phthalic acid) in a solution of ethanol and distilled water. The crystal structure was characterized by X-ray single-crystal diffraction and infrared spectrum. In 1, a novel 2D supramolecular structure was formed, containing water octamer and tetramer.
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